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Hexyl Cinnamic Aldehyde α Hexyl cinnamaldehyde Manufacturers, SDS MSDS Sheet
Hexyl Cinnamaldehyde
CAS: 101-86-0
Synonyms: α-n Hexyl Cinnamic Aldehyde, α-Hexyl cinnamaidehyde; α-n-Hexyl-β-Phenylacrolein; AHCA; HCA
Octanal, 2-(phenylmethylene)
EINECS Number: 202-983-3
HS Number: 2912290000
Molecular Weight: 216.32
Molecular Formula: C15H20O
Odor Profile: Floral, Jasmin, Waxy
Olfactory Description: Similar to alpha amyl cinnamic aldehyde but with a finer, more floral and
delicate character.
Visual Description: Clear yellow liquid
GC Analysis ------------- Min --- Max
trans isomer ------------ 90% --- 95%
cis isomer -------------- 3% ---- 8.5%
cis + trans isomers ----- 95%
Acid Value (mg KOH/gm)
-- 0 ----- 0.5
Flashpoint (closed cup) - > 100C
USES: Very extensively used in perfumes where it produces a jasmine-like floral when accompanied by more volatile chemicals of floral character. Blends easily and assists in fixation of the fragrance. It is also used in Soap, Acid Cleaner Liquid, Detergent, Alcoholic Lotion, Fabric Softener, Anti Perspirant, Foam Bath, Hard Surface Cleaner, Deo Stick, Shampoo, Bleach.
Hexyl Cinnamic Aldehyde, α Hexyl cinnamaidehyde SDS MSDS Sheet, Material Safety Data Sheet
1 - Product Identification
Product name: Hexyl Cinnamic Aldehyde
CAS Number 101-86-0
EINECS EC Number: 202-983-3
Molecular Formula: C6H5CH=C[(CH2)5CH3]CHO
Molecular Weight: 216.32
2 - Hazards identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Dermal (Category 5)
Skin irritation (Category 3)
Eye irritation (Category 2A)
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
Signal Words: Warning
Hazard statements:
H313: May be harmful in contact with skin.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation
Precautionary statements: P363, P501
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P363: Wash contaminated clothing before reuse.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P302+ P352 - IF ON SKIN: Wash with plenty of soap and water.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorized agents only.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbols: Xi Irritant
R Phrases: R36 Irritating to eyes. R21 Harmful in contact with skin. R43 May cause sensitisation by skin contact
S Phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S24 Avoid contact with skin. S28 After contact with skin, wash immediately with plenty of water.
3 - Composition / information on ingredients
Chemical Name: alpha-hexylcinnamaldehyde
CAS Number 101-86-0
EINECS EC Number: 202-983-3
4 - First aid measures
Eye contact: Immediately flush eyes with plenty of clean water for an extended time, not less than five (5) minutes. Flush longer if there is any indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a circular motion.
Skin contact: Immediately remove contaminated clothing and shoes. Wash the affected area with plenty of soap and water until no evidence of the chemical remains. Launder clothing before reuse. If irritation develops, call a physician.
Inhalation: If affected, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Ingestion: Do not induce vomiting. Rinse out the mouth with water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
5 - Fire fighting measures
NFPA flammability class: IIIB
Flash point: >212 °F (>100 °C) in Tag Closed Cup
Fire and explosive properties: Combustible liquid will burn at high temperatures.
Extinguishing media: NFPA Class IIIB (Combustible liquid): Use water spray, ABC dry chemical, foam or carbon dioxide. Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures.
Fire fighting instructions: Wear self-contained breathing apparatus (SCBA) equipped with a full face piece and operated in a pressure-demand mode (or other positive pressure mode) and approved protective clothing. Personnel without suitable respiratory protection must leave the area to prevent significant exposure to hazardous gases from combustion, burning or decomposition. In an enclosed or poorly ventilated area, wear SCBA during cleanup immediately after a fire as well as during the attack phase of fire fighting operations.
Unusual fire/explosion hazards: Irritating or toxic substances may be emitted upon burning, combustion or decomposition.
6 - Accidental release measures
Containment techniques: Prevent entry into sewers and waterways. Contain by diking with sand, earth or other non-combustible material. If spilled in an enclosed area, ventilate.
Clean-up techniques: Wear proper personal protective clothing and equipment. Do not flush liquid into public sewer, water systems or surface waters. Eliminate ignition sources. Soak up large spill residue and small spills with an inert absorbent. Place into labeled, closed container; store in safe location to await disposal. Change contaminated clothing and launder before reuse. Personal Protective Equipment must be worn.
7 - Handling and storage
Handling: Do not cut, puncture, or weld on or near the container. Wash thoroughly after handling this product. Always wash up before eating, smoking or using the facilities. Use under well-ventilated conditions. Avoid eye and skin contact. Avoid inhalation of aerosol, mist, spray, fume or vapor. Avoid drinking, tasting, swallowing or ingesting this product. Provide eyewash fountains and safety showers in the work area.
Storage: Empty container contains residual product which may exhibit hazards of product. Store cool and dry, under well-ventilated conditions. Do not store in open, unlabeled or mislabeled containers. Keep container closed when not in use. Product can easily oxidize. It is recommended that opened containers be padded with nitrogen. Keep away from heat, sparks and open flames.
8 - Exposure controls / personal protection
Engineering controls: Always provide effective general and, when necessary, local exhaust ventilation to draw fumes, vapors and/or dust away from workers to prevent routine inhalation. Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s). (Ventilation guidelines/techniques may be found in publications such as Industrial Ventilation: American Conference of Governmental Industrial Hygienists, 1330 Kemper Meadow Drive, Cincinnati, OH, 45240-1634, USA.)
Eye/face protection: Safety glasses or goggles required.
Skin protection: Wear chemical resistant (impervious) gloves. Wear long sleeve shirt and trousers and other equipment as needed to avoid skin contact.
Respiratory protection: Wear an approved respirator (e.g., an organic vapor respirator, a full face air purifying respirator for organic vapors, or a self-contained breathing apparatus) whenever exposure to aerosol, mist, spray, fume or vapor exceed the exposure limit(s) of any chemical substance listed in this MSDS. Use respirator in accordance with manufacturer's use limitations and OSHA standard 1910.134 (29CFR).
9 - Physical and chemical properties
Form: Liquid
pH: Not Available
Appearance Pale yellow
% Volatile by weight: 100%
Odor: Jasmine
Specific gravity: 0.95 - 0.96 (25C)
Solubility in water: Negligible
Evaporation rate: < 0.01
Vapor pressure: <0.02 mm Hg @20C
Boiling point F: 581F
Boiling point C: 305C
Melting point: 4C (39F)
10 - Stability and reactivity
Stability: This product is stable.
Hazardous polymerization: Hazardous polymerization will not occur.
Conditions to avoid: Excessive heat and ignition sources.
Incompatibility with other materials: Avoid contact with strong oxidizing agents.
Hazardous decomposition products: Carbon dioxide and carbon monoxide.
11 - Toxicological information
LC50 Inhalation: Not Established
LD50 Oral: 3100 mg/kg Rat/ adult
LD50 Skin: >3000 mg/kg Rabbit/ adult
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
12 - Ecological information
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
No other ecological testing has been conducted on this product.
13 - Disposal information
Incinerate waste product when in liquid form (i.e., as supplied) in a properly permitted (approved) incineration facility in accordance with local regulations. Liquids cannot be disposed of in a landfill. Do not release to waterways. Wash-water should be contained and sent to a waste facility for proper handling and disposal in accordance with all applicable regulations.
14 - Transportation information
US DOT & ADR/RID Classification: Not Regulated
Canada TDG Classification: Not Regulated
IATA: Not Regulated
15 - Regulatory information
USA federal:
OSHA: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4): Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.
SARA 304 Emergency release notification: Not regulated.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated.
SARA 302 Extremely hazardous substance: Not listed.
SARA 311/312 Hazardous chemical: No
SARA 313 (TRI reporting): Not regulated.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Not listed.
Canada Domestic Substances List (DSL): Yes
Canada Non-Domestic Substances List (NDSL): No
EINECS EC Number: 202-983-3
16 - Other information
Disclaimer
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Our company provides this Hexyl Cinnamic Aldehyde MSDS sheet
contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This Hexyl Cinnamaldehyde SDS sheet is
intended only as a guide to the appropriate precautionary handling of the
material by a properly trained person using this product. Individuals receiving
the information must exercise their independent judgment in determining its
appropriateness for a particular purpose.
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Hexyl Cinnamaldehyde manufacturers
Hexyl Cinnamic Aldehyde manufacturers at:
MUBY CHEMICALS
DONGRI-CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE)
91-22-23770100, 23726950, 23774610, 23723564, 91-22-23728264
e-mail: info@mubychem.com
Alpha α Hexyl Cinnamaldehyde Hexyl Cinnamic Aldehyde Exporters, Importers, Suppliers & Manufacturers
Hexyl Cinnamic Aldehyde α Hexyl cinnamaldehyde Manufacturers